MADISON, WI, MAY 18, 2009 Pharmaceuticals and personal care products (PPCPs) carried in biosolids (i.e., treated sewage sludge) may reach surface waters or groundwater when these materials are applied as fertilizer to agricultural land. During the high flow conditions created by land application of liquid municipal biosolids (LMB) the residence time of solutes in soil macropores may be too short for sorption equilibration which increases the risk for leaching. Physically based solute transport simulation models are widely used in environmental risk assessment for pesticides. These models may also be applicable for PPCPs when their physical and chemical properties and soil dissipation characteristics are available. However, these models do not account for non-equilibrium sorption in soil macropores. The model MACRO is one of the models used in environmental risk assessments for pesticides and may have potential as an environmental risk assessment tool for PPCPs.